JPS5855447A - 光学活性２−メチルブチルフエニル基を有するカルボン酸のシクロヘキサノ−ル誘導体 - Google Patents
光学活性２−メチルブチルフエニル基を有するカルボン酸のシクロヘキサノ−ル誘導体Info
- Publication number
- JPS5855447A JPS5855447A JP15163281A JP15163281A JPS5855447A JP S5855447 A JPS5855447 A JP S5855447A JP 15163281 A JP15163281 A JP 15163281A JP 15163281 A JP15163281 A JP 15163281A JP S5855447 A JPS5855447 A JP S5855447A
- Authority
- JP
- Japan
- Prior art keywords
- trans
- carboxylic acid
- methylbutyl
- cyclohexanol
- expressed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- HPXRVTGHNJAIIH-PTQBSOBMSA-N cyclohexanol Chemical class O[13CH]1CCCCC1 HPXRVTGHNJAIIH-PTQBSOBMSA-N 0.000 title claims abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title abstract description 3
- -1 2-methylbutylphenyl group Chemical group 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000004973 liquid crystal related substance Substances 0.000 abstract description 11
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract description 10
- 150000001875 compounds Chemical class 0.000 abstract description 9
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000463 material Substances 0.000 abstract description 5
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract description 5
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000003287 optical effect Effects 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- NNJMFJSKMRYHSR-UHFFFAOYSA-N 4-phenylbenzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=CC=C1 NNJMFJSKMRYHSR-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007796 conventional method Methods 0.000 abstract description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000203 mixture Substances 0.000 description 9
- GCFAUZGWPDYAJN-UHFFFAOYSA-N cyclohexyl 3-phenylprop-2-enoate Chemical compound C=1C=CC=CC=1C=CC(=O)OC1CCCCC1 GCFAUZGWPDYAJN-UHFFFAOYSA-N 0.000 description 8
- 239000004988 Nematic liquid crystal Substances 0.000 description 5
- 230000003098 cholesteric effect Effects 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 4
- WXBLLCUINBKULX-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1 WXBLLCUINBKULX-UHFFFAOYSA-N 0.000 description 4
- 235000010233 benzoic acid Nutrition 0.000 description 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004990 Smectic liquid crystal Substances 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 2
- 239000013065 commercial product Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- ILYSAKHOYBPSPC-UHFFFAOYSA-N 2-phenylbenzoic acid Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1 ILYSAKHOYBPSPC-UHFFFAOYSA-N 0.000 description 1
- LGORKSSOIBSSJH-GWEOLNPGSA-N C1CC(CCCCC)CCC1[C@@H]1CC[C@@H](O)CC1 Chemical compound C1CC(CCCCC)CCC1[C@@H]1CC[C@@H](O)CC1 LGORKSSOIBSSJH-GWEOLNPGSA-N 0.000 description 1
- 239000004986 Cholesteric liquid crystals (ChLC) Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- DQZKGSRJOUYVPL-UHFFFAOYSA-N cyclohexyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OC1CCCCC1 DQZKGSRJOUYVPL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 210000000744 eyelid Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229940098499 neotic Drugs 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 235000020334 white tea Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Crystal Substances (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15163281A JPS5855447A (ja) | 1981-09-25 | 1981-09-25 | 光学活性２−メチルブチルフエニル基を有するカルボン酸のシクロヘキサノ−ル誘導体 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15163281A JPS5855447A (ja) | 1981-09-25 | 1981-09-25 | 光学活性２−メチルブチルフエニル基を有するカルボン酸のシクロヘキサノ−ル誘導体 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5855447A true JPS5855447A (ja) | 1983-04-01 |
| JPH0210819B2 JPH0210819B2 (en]) | 1990-03-09 |
Family
ID=15522780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15163281A Granted JPS5855447A (ja) | 1981-09-25 | 1981-09-25 | 光学活性２−メチルブチルフエニル基を有するカルボン酸のシクロヘキサノ−ル誘導体 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5855447A (en]) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58154532A (ja) * | 1982-02-20 | 1983-09-14 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | ビシクロヘキシル誘導体 |
| US4526704A (en) * | 1982-07-28 | 1985-07-02 | Hoffmann-La Roche Inc. | Multiring liquid crystal esters |
| US4584120A (en) * | 1982-02-15 | 1986-04-22 | Hitachi, Ltd. | Liquid crystal compound and liquid crystal composition |
| US4613209A (en) * | 1982-03-23 | 1986-09-23 | At&T Bell Laboratories | Smectic liquid crystals |
| US4622165A (en) * | 1983-07-27 | 1986-11-11 | Alps Electric Co., Ltd | Liquid crystal mixture of a liquid crystal compound having a smectic C phase and an optically active compound |
-
1981
- 1981-09-25 JP JP15163281A patent/JPS5855447A/ja active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4584120A (en) * | 1982-02-15 | 1986-04-22 | Hitachi, Ltd. | Liquid crystal compound and liquid crystal composition |
| JPS58154532A (ja) * | 1982-02-20 | 1983-09-14 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | ビシクロヘキシル誘導体 |
| US4617140A (en) * | 1982-02-20 | 1986-10-14 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Bicyclohexyl derivatives |
| US4613209A (en) * | 1982-03-23 | 1986-09-23 | At&T Bell Laboratories | Smectic liquid crystals |
| US4526704A (en) * | 1982-07-28 | 1985-07-02 | Hoffmann-La Roche Inc. | Multiring liquid crystal esters |
| US4622165A (en) * | 1983-07-27 | 1986-11-11 | Alps Electric Co., Ltd | Liquid crystal mixture of a liquid crystal compound having a smectic C phase and an optically active compound |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0210819B2 (en]) | 1990-03-09 |
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